Primary secondary tertiary laboratory
WebHFSRB - Pag Lisensyado... ProtektaDOH WebPhSO 2Cl+HNHR→PhSO 2NHR KOH PhSO 2NKR(water soluble) (2) Secondary amine forms alkyl sulphonamide which does not form salt with alkali and hence remains insoluble (solid) in alkali solution. PhSO 2Cl+HNR 2→PhSO 2NR 2(water insoluble)→ no action. (3) Tertiary amines does not react with Hinsberg's reagent.
Primary secondary tertiary laboratory
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WebThe primary halide may take considerably longer to produce a precipitate. It is more difficult to explain the reason for this, because it needs a fairly intimate knowledge of the mechanisms involved in the reactions. It reflects the change in the way that the halide ion is produced as you go from primary to secondary to tertiary halogenoalkanes.
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